Web[Ir (dF (Me)ppy) 2 (dtbbpy)]PF 6 is a photocatalyst readily facilitates hydroamination of olefins as well as the decarboxylative arylation and vinylation of carboxylic acids via …
Visible‐Light‐Mediated Heterocycle Functionalization via
WebAug 28, 2024 · [Ir(dtbbpy)(ppy) 2]PF 6 (entry 3) afforded a trace of product 2. Significantly higher conversion was observed with fac -Ir(ppy) 3 (71 % conversion, entry 4) and similar … WebJun 8, 2015 · A visible-light-mediated procedure for the unprecedented trifluoromethylchlorosulfonylation of unactivated alkenes is presented. It uses [Cu(dap)2]Cl as catalyst, and contrasts with [Ru(bpy)3]Cl2, [Ir(ppy)2(dtbbpy)]PF6, or eosin Y that exclusively give rise to trifluoromethylchlorination of the same … smarownica na baterie
Ir(dtbbpy)(ppy)2 PF6 676525-77-2
WebJan 12, 2024 · Isolatedyield parentheses.DABCO: 1,4-diazabicyclo [2.2.2]octane; [Ir]-1: Ir(4-Fppy)2(bpy)PF6; [Ir]-2: Ir(ppy)2(dtbbpy)PF6; [Ir]-3: Ir(2,4-dFppy)2(bpy)PF6; [Ru]: Ru(bpy)3Cl2•6H2O. correspondingproducts were produced goodyields (3ja-3ma: 34%-87% yields). gram-scalereaction anilineacid-derived substrate reducedphotocatalyst loading ... WebJan 4, 2024 · Synonyms Chemsrc provides [Ir (dtbbpy) (ppy)2] [PF6] (CAS#:676525-77-2) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Articles of [Ir (dtbbpy) (ppy)2] [PF6] are included as well. >> amp version: [Ir (dtbbpy) (ppy)2] [PF6] WebJan 29, 2014 · The development of a room-temperature lignin degradation strategy consisting of a chemoselective benzylic oxidation with a recyclable oxidant ([4-AcNH-TEMPO]BF4) and a catalytic reductive C-O bond cleavage utilizing the photocatalyst [Ir(ppy)2(dtbbpy)]PF6 is described. hilfe hilfe/barcodepdf.htm